Enantioselective zinc-mediated conjugate alkynylation of saccharin-derived 1-aza-butadienes-Reference-Cited by-同舟云学术

Enantioselective zinc-mediated conjugate alkynylation of saccharin-derived 1-aza-butadienes

Published:2020 Issue:66 Volume:56 Page:9461-9464
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Blay Gonzalo¹²³⁴^ORCID,Castilla Alvaro¹²³⁴^ORCID,Sanz David¹²³⁴,Sanz-Marco Amparo¹²³⁴^ORCID,Vila Carlos¹²³⁴^ORCID,Muñoz M. Carmen⁵⁶⁷⁴^ORCID,Pedro José R.¹²³⁴^ORCID

Affiliation:

1. Departament de Química Orgànica

2. Facultat de Química, Universitat de València

3. 46100 Burjassot

4. Spain

5. Departament de Física Aplicada

6. Universitat Politècnica de València

7. E-46022 València

Abstract

Diethylzinc and a bis(hydroxyl)malonamide ligand allow the first conjugate alkynylation of α,β-unsaturated imines. Excellent enatioselectivities are obtained with aliphatic alkynes.

Funder

European Regional Development Fund

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC04221H

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