Ultrafast excited state relaxation dynamics of pyran-based D–π–A systems: solvent polarity controls the triplet state

Author:

Vineetha Pookalavan Karicherry1ORCID,Govind Chinju2ORCID,Karunakaran Venugopal23ORCID,Manoj Narayanapillai1ORCID

Affiliation:

1. Department of Applied Chemistry and Inter-University Centre for Nanomaterials and Devices, CUSAT, Kochi 682022, Kerala, India

2. Photosciences and Photonics Section, Chemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram 695 019, Kerala, India

3. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

Abstract

The excited state relaxation dynamics of V-shaped D–π–A systems, EAPBA and TPAPBA were investigated using steady-state and time-resolved spectroscopy along with theoretical optimization.

Funder

Cochin University of Science and Technology

Department of Science and Technology, Ministry of Science and Technology, India

University Grants Commission - South Eastern Regional Office

Department of Biotechnology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

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