Mechanistic investigations via DFT support the cooperative heterobimetallic C–H and O–H bond activation across TaIr multiple bonds
Author:
Affiliation:
1. Université de Toulouse et CNRS
2. INSA
3. UPS
4. UMR 5215
5. LPCNO
6. Laboratory of Chemistry
7. Catalysis
8. Polymers and Processes
9. C2P2 UMR 5265
10. Université de Lyon
Abstract
Tantalum and iridium join forces to promote the unconventional cooperative activation of unactivated C–H and O–H bonds across the two metals.
Funder
Centre National de la Recherche Scientifique
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03818K
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5. Diverse bimetallic mechanisms emerging from transition metal Lewis acid/base pairs: development of co-catalysis with metal carbenes and metal carbonyl anions
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