Theoretical study on CO2 reduction catalyzed by formate dehydrogenase using the cation radical of a bipyridinium salt with an ionic substituent as a co-enzyme
Author:
Affiliation:
1. School of Materials and Chemical Technology
2. Tokyo Institute of Technology
3. Yokohama 226-8502
4. Japan
5. Graduate School of Science
6. Osaka City University
7. Osaka 558-8585
8. Research Centre of Artificial Photosynthesis (ReCAP)
Abstract
Mechanism for formate dehydrogenase from Candida boidinii catalyzed CO2 reduction to formate with the cation radical of a 4,4′-bipyridinium salt with an ionic substituent as a co-enzyme was clarified by theoretical studies.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP05261B
Reference63 articles.
1. Smart CO 2 Transformation (SCOT) project in EU Seventh Framework Program, http://scotproject.org
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3. CeO2-catalyzed direct synthesis of dialkylureas from CO2 and amines
4. Catalytic CO2conversion to organic carbonates with alcohols in combination with dehydration system
5. Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO2
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1. Engineering of formate dehydrogenase for improving conversion potential of carbon dioxide to formate;World Journal of Microbiology and Biotechnology;2023-10-21
2. Engineering of formate dehydrogenase for improving conversion potential of carbon dioxide to formate;2023-07-13
3. Studies on the catalytic mechanism of formate dehydrogenase from Candida boidinii using isotope-labelled substrate and co-enzyme;Catalysis Today;2023-03
4. Mechanism of Formate Dehydrogenase Catalyzed CO2 Reduction with the Cation Radical of a 2,2′-Bipyridinium Salt Based on a Theoretical Approach;Bulletin of the Chemical Society of Japan;2022-12-15
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