Rotaxane synthesis exploiting the M(i)/M(iii) redox couple
Author:
Affiliation:
1. Department of Chemistry
2. University of Warwick
3. Coventry CV4 7AL
4. UK
Abstract
In the context of advancing the use of metal-based building blocks for the construction of new and interesting mechanically interlocked molecules, we herein describe the preparation of rhodium and iridium containing [2]rotaxanes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02648J
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2. Structures, Thermal Properties, and Reactivities of Cationic Rh–cod Complexes in Solid State (cod = 1,5-Cyclooctadiene);Inorganic Chemistry;2023-01-26
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4. Solution, Solid-State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low-Coordinate Rhodium(III) and Iridium(III) Complexes;Chemistry - A European Journal;2018-02-28
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