Coordination of a bis-histidine-oligopeptide to Re(i) and Ga(iii) in aqueous solution-Reference-Cited by-同舟云学术

Coordination of a bis-histidine-oligopeptide to Re(i) and Ga(iii) in aqueous solution

Published:2019 Issue:40 Volume:48 Page:15184-15191
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

De Tommaso Gaetano¹²³⁴,Malgieri Gaetano⁵⁶⁷⁸⁹^ORCID,De Rosa Lucia¹⁰¹¹¹²⁴^ORCID,Fattorusso Roberto⁵⁶⁷⁸⁹^ORCID,D'Abrosca Gianluca⁵⁶⁷⁸⁹^ORCID,Romanelli Alessandra¹³¹⁴¹⁵⁴^ORCID,Iuliano Mauro¹²³⁴,D'Andrea Luca Domenico¹⁰¹¹¹²⁴^ORCID,Isernia Carla⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. Department of Chemical Sciences

2. University of Naples “Federico II” Cupa Nuova Cintia

3. 21-80126 Naples

4. Italy

5. Department of Environmental

6. Biological and Pharmaceutical

7. Sciences and Technologies

8. University of Campania “L. Vanvitelli”

9. 43-81100 Caserta

10. Institute of Biostructure and Bioimaging

11. CNR

12. 16-80134 Naples

13. Department of Pharmaceutical Sciences

14. University of Milan

15. 21 - 20133 Milan

Abstract

We have spectroscopically analyzed the chemistry in aqueous solution and the properties of the histidine-based chelator pHis2 complexed to the fac-[Re(H₂O)₃(CO)₃]⁺ and Ga(iii) to unveil the molecular determinants of their coordination.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02406A

Reference32 articles.

1. Technetium and Gallium Derived Radiopharmaceuticals: Comparing and Contrasting the Chemistry of Two Important Radiometals for the Molecular Imaging Era

2. A Novel Organometallic Aqua Complex of Technetium for the Labeling of Biomolecules: Synthesis of [99mTc(OH2)3(CO)3]+ from [99mTcO4]- in Aqueous Solution and Its Reaction with a Bifunctional Ligand

3. Mono-, bi-, or tridentate ligands? The labeling of peptides with99mTc-carbonyls

4. N Functionalization of Metal and Organic Protected L-Histidine for a Highly Efficient, Direct Labeling of Biomolecules with [Tc(OH2)3(CO)3]+

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