Incorporating ion-specific van der Waals and soft repulsive interactions in the Poisson–Boltzmann theory of electrical double layers-Reference-Cited by-同舟云学术

Incorporating ion-specific van der Waals and soft repulsive interactions in the Poisson–Boltzmann theory of electrical double layers

Published:2023 Issue:32 Volume:25 Page:21708-21722
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Seal Aniruddha¹²^ORCID,Tiwari Utkarsh³²,Gupta Ankur⁴^ORCID,Govind Rajan Ananth²^ORCID

Affiliation:

1. School of Chemical Sciences, National Institute of Science Education and Research Bhubaneswar, Homi Bhabha National Institute, Khurda, Odisha 752050, India

2. Department of Chemical Engineering, Indian Institute of Science, Bengaluru, Karnataka 560012, India

3. Department of Chemical Engineering, Birla Institute of Technology and Science Pilani, K K Birla Goa Campus, Zuarinagar, Goa 403726, India

4. Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, USA

Abstract

Inclusion of ion-specific Lennard–Jones interactions into the Poisson–Boltzmann theory of electric double layers captures the formation of a Stern layer and leads to qualitatively correct predictions of the double layer capacitance.

Funder

Science and Engineering Research Board

Infosys Foundation

Department of Atomic Energy, Government of India

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00745F

Reference84 articles.

1. The Electrical Double Layer and the Theory of Electrocapillarity.