Phototransformation of 5-nitro-2-furaldehyde in aqueous solution. A laser flash photolysis and product analysis study
Author:
Affiliation:
1. Instituto Superior de Engenharia de Coimbra
2. 3030-199 Coimbra
3. Portugal
Abstract
The photoreactivity of 5-nitro-2-furaldehyde in solution is ascribed to the lowest triplet state. Evidence that a furyloxyl radical yields 5-hydroxymethyl-2(5H)-furanone, and the radical anion leads to the novel product 5-imino-2(5H)-furanone in water, is presented.
Publisher
Springer Science and Business Media LLC
Subject
Physical and Theoretical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/PP/C6PP00423G
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