Synthesis, bridgehead functionalization, and photoisomerization of 9,10-diboratatriptycene dianions-Reference-Cited by-同舟云学术

Synthesis, bridgehead functionalization, and photoisomerization of 9,10-diboratatriptycene dianions

Published:2023 Issue:20 Volume:14 Page:5316-5322
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Prey Sven E.¹,Gilmer Jannik¹,Teichmann Samira V.¹,Čaić Luis¹,Wenisch Mischa¹,Bolte Michael¹^ORCID,Virovets Alexander¹^ORCID,Lerner Hans-Wolfram¹^ORCID,Fantuzzi Felipe²^ORCID,Wagner Matthias¹^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie, Goethe-Universität Frankfurt, Max-von-Laue-Straße 7, D-60438 Frankfurt am Main, Germany

2. School of Chemistry and Forensic Science, University of Kent, Park Wood Rd, Canterbury CT2 7NH, UK

Abstract

9,10-Diboratatriptycene dianions were synthesized via [4 + 2] cycloaddition between 9,10-dihydro-9,10-diboraanthracene dianions and benzyne. We show bridgehead chlorination, Me2S-adduct formation, and photorearrangement to diborabenzo[a]fluoranthenes.

Funder

Deutscher Akademischer Austauschdienst

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00555K

Reference58 articles.

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