Switching the hydrogenation selectivity of urea derivatives <i>via</i> subtly tuning the amount and type of additive in the catalyst system-Reference-Cited by-同舟云学术

Switching the hydrogenation selectivity of urea derivatives via subtly tuning the amount and type of additive in the catalyst system

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhu Jun¹,Wang Yongtao¹^ORCID,Yao Jia¹^ORCID,Li Haoran¹²^ORCID

Affiliation:

1. Department of Chemistry, ZJU-NHU United R&D Center, Zhejiang University, Hangzhou 310027, China

2. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Abstract

We have developed a triphos-Ru catalytic system that can switch the chemoselectivity in catalytic hydrogenation of urea derivatives (from N-formamides to N-monomethylamines and methanol) by changing only 0.5 mol% KOtBu (2% to 1.5%).

Funder

Fundamental Research Funds for the Central Universities

National Key Research and Development Program of China

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05674K

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