A ternary Rh complex catalyst highly active and stable in the hydrogenation of acrylonitrile–butadiene rubber
Author:
Affiliation:
1. State Key Laboratory of Organic-Inorganic Composites
2. Beijing University of Chemical Technology
3. Beijing 100029
4. China
5. Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials
Abstract
A ternary Rh-base catalyst, T-Rh-PPh3, shows better resistance to oxidation than RhCl(PPh3)3, ascribed to the phenolic hydroxyl structures in tannin.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C4NJ01627K
Reference21 articles.
1. Homogeneous Hydrogenation Art of Nitrile Butadiene Rubber: A Review
2. A detailed study of the hydrogenation of nitrile-butadiene rubber and other substrates catalyzed by Ru(II) complexes
3. Size-selective hydrogenation of NBR polymers catalyzed by pore-size controlled smectites loaded with palladium
4. Hydrogenation of acrylonitrile-butadiene rubber latex using in situ synthesized RhCl(PPh3)3 catalyst
5. Recovery of Wilkinson's catalyst from polymer based matrix using carbon dioxide expanded methanol
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