Effect of hydrogen bonds and π⋯π interactions on the crystallization of phenyl-perfluorophenyl amides: understanding the self-organization of a cocrystal

Author:

Pagliari Anderson B.1ORCID,Meyer Alexandre R.1ORCID,Solner Vanessa B.1,Rosa Jéssica M. L.1,Hörner Manfredo1,Bonacorso Helio G.1ORCID,Zanatta Nilo1ORCID,Martins Marcos A. P.1ORCID

Affiliation:

1. Núcleo de Química de Heterociclos (NUQUIMHE), Department of Chemistry, Federal University of Santa Maria (UFSM), 7105-900, Santa Maria, RS, Brazil

Abstract

Crystallization mechanisms were proposed to investigate hydrogen bond and aromatic donor–acceptor interactions in a series of phenyl–perfluorophenyl amides. The modulation of NH⋯OC bonds and aryl complementarity drove a new cocrystal growth.

Funder

Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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