Manganese(ii) complexes of tetradentate 4N ligands with diazepane backbones for catalytic olefin epoxidation: effect of nucleophilicity of peroxo complexes on reactivity

Author:

Saravanan Natarajan123,Sankaralingam Muniyandi123,Palaniandavar Mallayan456

Affiliation:

1. School of Chemistry

2. Bharathidasan University

3. Tiruchirappalli 620 024, India

4. Department of Chemistry

5. Central University of Tamil Nadu

6. Thiruvarur - 610 004, India

Abstract

Mononuclear Mn(ii) complexes of linear 4N ligands have been studied as catalysts for deformylation of aldehydes and epoxidation (H2O2) of unfunctionalised olefins to understand the role of ligand stereoelectronic factors.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference73 articles.

1. R. A. Johnson and K. B.Sharpless , in Catalytic Asymmetric Synthesis , ed. I. Ojima , VCH , New York , 1993 , ch. 1

2. E. N. Jacobsen , in Catalytic Asymmetric Synthesis , ed. I. Ojima , VCH , New York , 1993 , ch. 2

3. Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage

4. Catalytic asymmetric oxidations using optically active (salen)manganese(III) complexes as catalysts

5. Asymmetric olefin epoxidation with sodium hypochlorite catalyzed by easily prepared chiral manganese(III) salen complexes

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