Triplet sensitization enables bidirectional isomerization of diazocine with 130 nm redshift in excitation wavelengths-Reference-Cited by-同舟云学术

Triplet sensitization enables bidirectional isomerization of diazocine with 130 nm redshift in excitation wavelengths

Published:2023 Issue:34 Volume:14 Page:9161-9166
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Isokuortti Jussi¹,Griebenow Thomas²,Glasenapp Jan-Simon von²,Raeker Tim³^ORCID,Filatov Mikhail A.⁴^ORCID,Laaksonen Timo¹⁵,Herges Rainer²^ORCID,Durandin Nikita A.¹^ORCID

Affiliation:

1. Faculty of Engineering and Natural Sciences, Tampere University, FI-33101 Tampere, Finland

2. Otto-Diels-Institute of Organic Chemistry, Christian-Albrechts-University of Kiel, 24098 Kiel, Germany

3. Institute for Physical Chemistry, Department for Theoretical Chemistry, Christian-Albrechts-University of Kiel, 24098 Kiel, Germany

4. School of Chemical and Pharmaceutical Sciences, Technological University Dublin, City Campus, Grangegorman, Dublin 7, Ireland

5. Drug Research Program, Division of Pharmaceutical Biosciences, Faculty of Pharmacy, University of Helsinki, Finland

Abstract

Diazocine (bridged azobenzene) can be switched in both directions upon selective excitation of two different coexisting triplet sensitizers. Compared to direct irradiation, both switching wavelengths are strongly (≥130 nm) bathochromically shifted.

Funder

H2020 European Research Council

Luonnontieteiden ja Tekniikan Tutkimuksen Toimikunta

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02681G

Reference58 articles.

1. Highly Efficient Reversible Z−E Photoisomerization of a Bridged Azobenzene with Visible Light through Resolved S1(nπ*) Absorption Bands

2. Photoswitching of Diazocines in Aqueous Media