Understanding exo-selective Diels–Alder reactions involving Fischer-type carbene complexes

Author:

Cabrera-Trujillo Jorge Juan12345ORCID,Fernández Israel12345ORCID

Affiliation:

1. Departamento de Química Orgánica I and Centro de Innovación en Química Avanzada (ORFEO-CINQA)

2. Facultad de Ciencias Químicas

3. Universidad Complutense de Madrid

4. 28040-Madrid

5. Spain

Abstract

Exo-selective Diels–Alder cycloaddition reactions can be successfully achieved by the proper selection of an initial Fischer carbene complex.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference76 articles.

1. Synthesen in der hydroaromatischen Reihe

2. F. Fringuelli and A.Taticchi , The Diels-Alder Reaction: Selected Practical Methods , John Wiley & Sons, Ltd. , Hoboken, NJ , 2002

3. S. Sankararaman , Pericyclic Reactions - A Textbook: Reactions, Applications and Theory , Wiley , Weinheim , 2005

4. The Diels-Alder Reaction in Total Synthesis

5. Recent Advances in Natural Product Synthesis by Using Intramolecular Diels−Alder Reactions

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