Supramolecular control of transition metal complexes in water by a hydrophobic cavity: a bio-inspired strategy

Author:

Bistri Olivia12345,Reinaud Olivia12345

Affiliation:

1. Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques

2. UMR CNRS 8601

3. Université Paris Descartes

4. Sorbonne Paris Cité

5. 75006 Paris, France

Abstract

Different strategies for obtaining water-soluble cavity-appended metal complexes are described, and their resulting interlocked assets are discussed in relationship with the very specific properties of water as a solvent.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference83 articles.

1. I. Bertini , H. B.Gray , E. I.Stiefel and J. S.Valentine , Biological Inorganic Chemistry, Structure and Reactivity , University Science Books , Sausalito, CA , 2007

2. S. J. Lippard and J. M.Berg , Principles of Bioinorganic Chemistry , University Science Books , Mill-Valley, CA , 1994

3. Structural and Functional Aspects of Metal Sites in Biology

4. Anion recognition in water

5. Inside Cover: Graphene-Supported Ultrafine Metal Nanoparticles Encapsulated by Mesoporous Silica: Robust Catalysts for Oxidation and Reduction Reactions (Angew. Chem. Int. Ed. 1/2014)

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