Gas-phase pyrolysis of trans 3-pentenenitrile: competition between direct and isomerization-mediated dissociation

Author:

Mishra Piyush1234ORCID,Fritz Sean M.1234,Herbers Sven1234,Mebel Alexander M.1564ORCID,Zwier Timothy S.12347ORCID

Affiliation:

1. Department of Chemistry

2. Purdue University

3. West Lafayette

4. USA

5. Florida International University

6. Miami

7. Combustion Research Facility

Abstract

The flash pyrolysis of trans 3-pentenenitrile was studied by mass-correlated broadband microwave spectroscopy, where both molecular and radical species were observed within our jet-cooled molecular beam, including 2,4-pentadienenitrile.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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