Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions-Reference-Cited by-同舟云学术

Palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones for the synthesis of trans cycloalkanols through dynamic kinetic resolution under acidic conditions

Published:2020 Issue:43 Volume:56 Page:5815-5818
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Xiang¹²³⁴⁵,Zhao Zi-Biao⁵⁶⁷⁸⁴^ORCID,Chen Mu-Wang⁵⁶⁷⁸⁴^ORCID,Wu Bo⁵⁶⁷⁸⁴,Wang Han¹²³⁴,Yu Chang-Bin⁵⁶⁷⁸⁴^ORCID,Zhou Yong-Gui¹²³⁴⁵^ORCID

Affiliation:

1. Zhang Dayu School of Chemistry

2. Dalian University of Technology

3. Dalian 116024

4. P. R. China

5. State Key Laboratory of Catalysis

6. Dalian Institute of Chemical Physics

7. Chinese Academy of Sciences

8. Dalian 116023

Abstract

The first efficient palladium-catalyzed asymmetric hydrogenation of 2-aryl cyclic ketones has been described through dynamic kinetic resolution under acidic conditions, providing a facile access to chiral trans cycloalkanols.

Funder

Chinese Academy of Sciences Key Project

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC00480D

Reference79 articles.

1. Stereocontrolled Preparation of Fully Substituted Cyclopentanes: Relevance to Total Synthesis

2. Recent Developments in the Stereocontrolled Synthesis of Highly Substituted Cyclopentane Core Structures: From Drug Discovery Research to Natural Product Synthesis

3. Synthesis of Chiral Cyclopentenones

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