Asymmetric imino-acylation of alkenes enabled by HAT-photo/nickel cocatalysis-Reference-Cited by-同舟云学术

Asymmetric imino-acylation of alkenes enabled by HAT-photo/nickel cocatalysis

Published:2023 Issue:23 Volume:14 Page:6449-6456
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Rui¹,Wang Chuan¹^ORCID

Affiliation:

1. Hefei National Laboratory for Physical Science at the Microscale, Department of Chemistry, Center for Excellence in Molecular Synthesis, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, P. R. China

Abstract

By merging nickel-mediated aza-Heck cyclization and HAT-photo-promoted acyl C–H activation, an unprecedented highly enantioselective imino-acylation of oxime ester-tethered alkenes with aldehydes as the acyl source has been developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01945D

Reference114 articles.

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2. Recent developments in the use of aza-Heck cyclizations for the synthesis of chiral N-heterocycles

3. Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry