The ligand redox behavior and role in 1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene nickel–TMA(MAO) systems for ethylene polymerization

Author:

Gao Wei12345,Xin Lan12345,Hao Zhiqiang12345,Li Guodong6375,Su Ji-Hu89105,Zhou Lijing6375,Mu Ying12345

Affiliation:

1. State Key Laboratory for Supramolecular Structure and Materials

2. School of Chemistry

3. Jilin University

4. Changchun

5. China

6. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

7. Changchun 130012

8. Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics

9. University of Science and Technology of China

10. Hefei

Abstract

The BIAN ligand in the BIAN nickel–TMA(MAO) system is redox-active and plays a more important role than just acting as a neutral ligand.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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