Interesting fluorine anion water clusters [F−·(H2O)n] in metal complex crystals
Author:
Affiliation:
1. School of Chemical Engineering and Pharmaceutics
2. Henan University of Science and Technology
3. Luoyang
4. P. R. China
Abstract
Three crystalline complexes containing fluorine anion water cluster were reported. The fluoride anions and water molecules are H-bonded to each other in an alternating fashion within the fluoride–water hybrid cluster, where a fluoride anion plays the important role.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CE/C8CE00532J
Reference54 articles.
1. Coexistence of Planar and Chair-Shaped Cyclic Water Hexamers in a Unique Cyclohexanehexacarboxylate-Bridged Metal−Organic Framework
2. Bulk-Like Features in the Photoemission Spectra of Hydrated Doubly Charged Anion Clusters
3. Spectroscopic Determination of the OH − Solvation Shell in the OH − ·(H 2 O) n Clusters
4. Structure and dynamics of hydrated ions
5. Clusters: Structure, Energetics, and Dynamics of Intermediate States of Matter
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