Chiroptical switching behavior of heteroleptic ruthenium complexes bearing acetylacetonato and tropolonato ligands-Reference-Cited by-同舟云学术

Chiroptical switching behavior of heteroleptic ruthenium complexes bearing acetylacetonato and tropolonato ligands

Published:2021 Issue:41 Volume:50 Page:14611-14617
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yoshida Jun¹^ORCID,Yamazaki Kana²,Tateyama Kazunori²,Yuge Hidetaka²,Sato Hisako³^ORCID

Affiliation:

1. Department of Chemistry, College of Humanities & Sciences, Nihon University, 3-25-40 Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan

2. Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato Minami-ku, Sagamihara, 252-0373, Japan

3. Graduate School of Science and Engineering, Ehime University, 2-5 Bunkyo-chou, Matsuyama, Ehime 790-8577, Japan

Abstract

Heteroleptic ruthenium complexes exhibit relatively large ECD changes upon oxidation, long lifetime of the oxidized state, and quite slow racemization behavior.

Funder

Japan Science and Technology Agency

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02592A

Reference60 articles.

1. Synthesis of binuclear (.beta.-diketonato)ruthenium(III) complexes through introduction of an ethynyl group at a .gamma.-position of tris(.beta.-diketonato)ruthenium(III) and electrochemistry of the binuclear complexes

2. Where Is the Spin? Understanding Electronic Structure and g-Tensors for Ruthenium Complexes with Redox-Active Quinonoid Ligands

3. Metal-Induced Thiophene Ring Opening and CC Bond Formation To Produce Unique Hexa-1,3,5-trienediyl-Coupled Non-Innocent Ligand Chelates

4. The Electron-Rich {Ru(acac)2} Directed Varying Configuration of the Deprotonated Indigo and Evidence for Its Bidirectional Noninnocence

5. Valence-State Alternatives in Diastereoisomeric Complexes [(acac)2Ru(μ-QL)Ru(acac)2]n (QL2− = 1,4-Dioxido-9,10-anthraquinone,n = +2, +1, 0, −1, −2)

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