Synthesis of 5-aryl-3,3′-bis-indolyl and bis-7-aza-indolyl methanone derivatives from 5-bromo-7-azaindoles <i>via</i> sequential methylenation using microwave irradiation, CAN oxidation, and Suzuki coupling reactions-Reference-Cited by-同舟云学术

Synthesis of 5-aryl-3,3′-bis-indolyl and bis-7-aza-indolyl methanone derivatives from 5-bromo-7-azaindoles via sequential methylenation using microwave irradiation, CAN oxidation, and Suzuki coupling reactions

Published:2022 Issue:47 Volume:12 Page:30712-30721
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Pavithra Elavarasan¹,Kannadasan Sathananthan¹^ORCID,Shanmugam Ponnusamy²^ORCID

Affiliation:

1. Department of Chemistry, School of Advanced Sciences, VIT, Vellore-632014, India

2. Organic and Bioorganic Chemistry Division, CSIR-Central Leather Research Institute (CLRI), Adyar, Chennai-600020, India

Abstract

A catalyst-free methylenation of 7-aza indoles under MW irradiation and CAN oxidation of methylenated products to the respective ketones are achieved. Plausible mechanisms of the reactions and photophysical properties of the products are described.

Funder

Science for Equity, Empowerment and Development Division

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA05849A

Reference82 articles.

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