Photoinduced charge-transfer in chromophore-labeled gold nanoclusters: quantum evidence of the critical role of ligands and vibronic couplings-Reference-Cited by-同舟云学术

Photoinduced charge-transfer in chromophore-labeled gold nanoclusters: quantum evidence of the critical role of ligands and vibronic couplings

Published:2021 Issue:14 Volume:13 Page:6786-6797
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Domínguez-Castro Adrian¹²³^ORCID,Lien-Medrano Carlos R.¹²³^ORCID,Maghrebi Khaoula⁴⁵⁶⁷⁸,Messaoudi Sabri⁴⁵⁶⁷⁸,Frauenheim Thomas¹²³⁹¹⁰,Fihey Arnaud¹¹¹²¹³¹⁴¹⁵^ORCID

Affiliation:

1. Bremen Center for Computational Materials Science (BCCMS)

2. Universität Bremen

3. Germany

4. Faculty of Sciences of Bizerte FSB

5. Carthage University

6. 7021 Jarzouna

7. Tunisia

8. Laboratory of Materials

9. Beijing Computational Research Center (CSRC)

10. Beijing

11. Univ Rennes

12. CNRS

13. ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226

14. F-35000 Rennes

15. France

Abstract

We present the first application of the time-dependent density functional tight-binding method to rationalize the photo-induced electron transfer in an experimental hexyl-protected Au₂₅ cluster labeled with a pyrene fluorophore.

Funder

Deutsche Forschungsgemeinschaft

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NR/D1NR00213A

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1. Atomically Precise Noble Metal Nanoclusters as Efficient Catalysts: A Bridge between Structure and Properties

2. Water-soluble Au 13 clusters protected by binary thiolates: Structural accommodation and the use for chemosensing