Directed gas-phase preparation of the elusive phosphinosilylidyne (SiPH2, X2A′′) and cis/trans phosphinidenesilyl (HSiPH; X2A′) radicals under single-collision conditions-Reference-Cited by-同舟云学术

Directed gas-phase preparation of the elusive phosphinosilylidyne (SiPH2, X2A′′) and cis/trans phosphinidenesilyl (HSiPH; X2A′) radicals under single-collision conditions

Published:2021 Issue:34 Volume:23 Page:18506-18516
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

He Chao¹,Goettl Shane J.¹^ORCID,Yang Zhenghai¹,Doddipatla Srinivas¹,Kaiser Ralf I.¹^ORCID,Silva Mateus Xavier²^ORCID,Galvão Breno R. L.²^ORCID

Affiliation:

1. Department of Chemistry, University of Hawai’i at Manoa, Honolulu, Hawaii, 96822, USA

2. Centro Federal de Educação Tecnológica de Minas Gerais, CEFET-MG, Av. Amazonas 5253, 30421-169 Belo Horizonte, Minas Gerais, Brazil

Abstract

Center-of-mass flux contour map for the reactions of the D1-silylidyne radical (SiD; X2Π) with phosphine (PH3; X1A1) leading to the formation of phosphinidenesilyl (HSiPH/DSiPH) and phosphinosilylidyne (SiPH2).

Funder

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

National Science Foundation

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP02812J

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