In situ compatibilisation of alkenyl-terminated polymer blends using cross metathesis-Reference-Cited by-同舟云学术

In situ compatibilisation of alkenyl-terminated polymer blends using cross metathesis

Published:2015 Issue:13 Volume:5 Page:9658-9666
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Descour C.¹²³⁴⁵,Macko T.⁶⁷⁸⁹¹⁰,Schreur-Piet I.¹²³⁴⁵,Pepels M. P. F.¹²³⁴⁵,Duchateau R.¹²³⁴⁵

Affiliation:

1. Eindhoven University of Technology

2. Department of Chemical

3. Engineering and Chemistry

4. Polymer Chemistry Group

5. 5600 MB Eindhoven

6. Division Plastics

7. Fraunhofer Institute for Structural Durability and System Reliability LBF

8. Materials Analytics

9. 64289 Darmstadt

10. Germany

Abstract

A whiff of diblocks is enough! Straightforward coupling of two vinyl-terminated macromolecules was achieved by cross metathesis (CM) using Grubbs' second-generation catalyst (G2) giving access to a diversity of “self-compatibilised” polymer blends. Solution blends, in the absence of G2, showed clear macrophase separation while metathesized samples no longer did. A small fraction of diblocks only proved to act as an excellent compatibilizer.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA11056K

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