An antiferromagnetic metalloring pyrazolate (Pz) framework with [Cu12(μ2-OH)12(Pz)12] nodes for separation of C2H2/CH4 mixture

Author:

Li Ziyin12345,Ye Yingxiang12345ORCID,Yao Zizhu12345,Guo Junzhi12345,Lin Quanjie12345,Zhang Jindan12345,Zhang Zhangjing12345,Wei Fangfang12345,Xiang Shengchang12345ORCID

Affiliation:

1. Fujian Provincial Key Laboratory of Polymer Materials

2. College of Chemistry and Materials Science

3. Fujian Normal University

4. Fuzhou 350007

5. PR China

Abstract

An antiferromagnetic pyrazolate (Pz) MROF-12 with cyclic-type [Cu122-OH)12(Pz)12] clusters and new topology of the Schläfli symbol {460.66} was reported for the separation of C2H2/CH4 or CO2/CH4 mixture.

Funder

National Natural Science Foundation of China

Fujian Provincial Department of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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