Facile synthesis of α-aminoboronic acids from amines and potassium acyltrifluoroborates (KATs) via trifluoroborate-iminiums (TIMs)-Reference-Cited by-同舟云学术

Facile synthesis of α-aminoboronic acids from amines and potassium acyltrifluoroborates (KATs) via trifluoroborate-iminiums (TIMs)

Published:2018 Issue:23 Volume:9 Page:5191-5196
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shiro Tomoya¹²³⁴⁵,Schuhmacher Anne¹²³⁴⁵,Jackl Moritz K.¹²³⁴⁵,Bode Jeffrey W.¹²³⁴⁵^ORCID

Affiliation:

1. Laboratorium fur Organische Chemie

2. Department of Chemistry and Applied Biosciences

3. ETH Zurich

4. Zürich

5. Switzerland 8093

Abstract

We report the formation of iminium-trifluoroborates (TIMs) from potassium acyltrifluoroborates (KATs) and the synthesis of α-aminotrifluoroborates and α-aminoboronic acids from TIMs.

Funder

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01486H

Reference54 articles.

1. Boronic acids in medicinal chemistry: anticancer, antibacterial and antiviral applications

2. Boron Containing Compounds as Protease Inhibitors

3. Aminophosphonic and Aminoboronic Acids as Key Elements of a Transition State Analogue Inhibitor of Enzymes

4. Structure-based design of a potent transition state analogue for TEM-1 β-lactamase

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