The K2(9-ethylguanine)122+ quadruplex is more stable to unimolecular dissociation than the K(9-ethylguanine)8+ quadruplex in the gas phase: a BIRD, energy resolved SORI-CID, IRMPD spectroscopic, and computational study

Author:

Azargun Mohammad1234,Meister Paul J.5674,Gauld James W.5674ORCID,Fridgen Travis D.1234ORCID

Affiliation:

1. Department of Chemistry

2. Memorial University of Newfoundland

3. St. John's

4. Canada

5. Department of Chemistry and Biochemistry

6. University of Windsor

7. Windsor

Abstract

A combination of experimental trapped-ion mass spectrometric studies and computational chemistry has been used to assess the intrinsic properties of the potassiated 9-ethylguanine (9eG) self-assembled quadruplex, K2(9eG)122+, in the gas phase.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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