Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt

Author:

Rysak Vincent12345,Dixit Ruchi678910,Trivelli Xavier121134,Merle Nicolas12345ORCID,Agbossou-Niedercorn Francine12345ORCID,Vanka Kumar6789ORCID,Michon Christophe12345ORCID

Affiliation:

1. Univ. Lille

2. CNRS

3. Centrale Lille

4. Univ. Artois

5. UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide

6. Physical and Material Chemistry Division

7. CSIR-National Chemical Laboratory

8. Pune 411008

9. India

10. Academy of Scientific and Innovative Research (AcSIR)

11. INRA

Abstract

A fluorinated borate BArF salt catalyses the reductive deoxygenation of esters to ethers by using hydrosilanes. Experimental and theoretical studies highlight the role of noncovalent interactions in the reaction mechanism.

Funder

Centre National de la Recherche Scientifique

Université Lille 1 - Sciences et Technologies

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

European Commission

Institute Pasteur De Lille

Institut Chevreul

Région Hauts-de-France

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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3. H. Feuer and J.Hooz , in The Chemistry of the Ether Linkage , ed. S. Patai , Interscience , London , 1967

4. J. March , Advanced Organic Chemistry, Reactions, Mechanisms and Structure , Wiley , New York , 4th edn, 1992

5. L. Karas and W. J.Piel , “Ethers” in Kirk-Othmer Encyclopedia of Chemical Technology , Wiley , New York , 2000

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