Divergent pathway and reactivity control of intramolecular arene C–H vinylation by vinyl cations-Reference-Cited by-同舟云学术

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Divergent pathway and reactivity control of intramolecular arene C–H vinylation by vinyl cations

Published:2019 Issue:41 Volume:17 Page:9135-9139
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Li Xin¹²³⁴,Zhang Shuo-Qing¹²³⁴,Hong Xin¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Zhejiang University

3. Hangzhou 310027

4. China

Abstract

A computational study revealed the mechanistic details and controlling factors of reactivity in intramolecular C–H vinylation through a vinyl cation intermediate.

Funder

National Natural Science Foundation of China

China Postdoctoral Science Foundation

Fundamental Research Funds for the Central Universities

Zhejiang University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01916B

Reference19 articles.

1. Photogenerated carbonium ions and vinyl cations in aqueous solution

2. Solvolysis of Vinyl Iodonium Salts. New Insights into Vinyl Cation Intermediates

3. Generation of Cycloalkynes by Hydro-Iodonio-Elimination of Vinyl Iodonium Salts

4. Are Vinyl Cations Finally Coming of Age?

5. Reactions of nitropolymethylbiphenyls

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