Axial modulation of Fe sites realizing high-performance oxygen reduction reaction of FeN<sub>4</sub>catalysts-Reference-Cited by-同舟云学术

Axial modulation of Fe sites realizing high-performance oxygen reduction reaction of FeN₄catalysts

Published:2023 Issue:21 Volume:11 Page:11326-11333
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Zhang Yu¹²,Li Caixia¹³,Li Jin¹²,Liu Xiaoni¹³,Li Guangjiu²,Li Bin¹,Wang Lei¹²³^ORCID

Affiliation:

1. State Key Laboratory Base of Eco-Chemical Engineering, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

2. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

3. Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection, College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao, 266042, P. R. China

Abstract

The introduction of axial S atoms optimizes the FeN4active center, moves the d-band center away from the Fermi energy level, weakens the adsorption of intermediates, and improves its catalytic performance.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA10062B

Reference50 articles.

1. Zirconium nitride catalysts surpass platinum for oxygen reduction

2. MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions