Hydrodeoxygenation of guaiacol over bimetallic Fe-alloyed (Ni, Pt) surfaces: reaction mechanism, transition-state scaling relations and descriptor for predicting C–O bond scission reactivity-Reference-Cited by-同舟云学术

Hydrodeoxygenation of guaiacol over bimetallic Fe-alloyed (Ni, Pt) surfaces: reaction mechanism, transition-state scaling relations and descriptor for predicting C–O bond scission reactivity

Published:2018 Issue:8 Volume:8 Page:2146-2158
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Liu Xiaoyang¹²³⁴,An Wei¹²³⁴^ORCID,Wang Yixing¹²³⁴,Turner C. Heath⁵⁶⁷⁸,Resasco Daniel E.⁹¹⁰¹¹¹²⁸

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Shanghai University of Engineering Science

3. Shanghai 201620

4. China

5. Department of Chemical and Biological Engineering

6. University of Alabama

7. Tuscaloosa

8. USA

9. School of Chemical

10. Biological and Materials Engineering and Center for Biomass Refining

11. University of Oklahoma

12. Norman

Abstract

Small means big: DFT-calculated C–O bond length of adsorbed intermediates can serve as a good descriptor for predicting the C–O bond scission reactivity of phenolics over metal catalysts.

Funder

Division of Chemical, Bioengineering, Environmental, and Transport Systems

National Natural Science Foundation of China

Shanghai University of Engineering Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY00282G

Reference96 articles.

1. Catalytic Transformation of Lignin for the Production of Chemicals and Fuels