The Malaprade reaction mechanism for ethylene glycol oxidation by periodic acid based on density functional theory (DFT)-Reference-Cited by-同舟云学术

The Malaprade reaction mechanism for ethylene glycol oxidation by periodic acid based on density functional theory (DFT)

Published:2023 Issue:32 Volume:25 Page:21448-21455
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kołodziejczyk Agata¹,Błaziak Mikołaj²,Podgórniak Kinga³⁴,Jezierska Aneta⁵^ORCID,Błaziak Kacper³⁴^ORCID

Affiliation:

1. Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw 01-224, Poland

2. Department of Cardiology, Wroclaw Medical University, ul. Pasteura 4, 50-367 Wroclaw, Poland

3. Faculty of Chemistry, University of Warsaw, ul. Pasteura 1, 01-224 Warsaw, Poland

4. Biological and Chemical Research Center, University of Warsaw, ul. Żwirki i Wigury 101, 01-224 Warsaw, Poland

5. University of Wrocław, Faculty of Chemistry, ul. F. Joliot-Curie 14, 50-383 Wrocław, Poland

Abstract

A general mechanism of the Malaprade oxidative carbon–carbon bond cleavage reaction of α-glycol in the presence of periodic acid has been proposed on the basis of density functional theory (DFT) computations.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP04764K

Reference46 articles.

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2. A. S.Perlin , in Adv. Carbohydr. Chem. Biochem. , ed. D. Horton , Academic Press , 2006 , vol. 60, pp. 183–250

3. Periodate oxidation of polysaccharides for modification of chemical and physical properties

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