Insight into catalytic reduction of CO2to methane with silanes using Brookhart's cationic Ir(iii) pincer complex-Reference-Cited by-同舟云学术

Insight into catalytic reduction of CO2to methane with silanes using Brookhart's cationic Ir(iii) pincer complex

Published:2018 Issue:17 Volume:8 Page:9232-9242
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Fang Shaoqin¹²³⁴⁵,Chen Hongcai¹²³⁴⁵,Wei Haiyan¹²³⁴⁵^ORCID

Affiliation:

1. Jiangsu Key Laboratory of Biofunctional Materials

2. School of Chemistry and Materials Science

3. Jiangsu Provincial Key Laboratory for NSLSCS

4. Nanjing Normal University

5. Nanjing 210097

Abstract

The transformation of CO₂and silanes to methane catalyzed by a cationic Ir–pincer complex is investigated and divided into four reducing steps. The first step is the rate-determining step of the overall catalytic cycle.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C7RA13486J

Reference122 articles.

1. M.Aresta , Carbon Dioxide: Utilization Options to Reduce its Accumulation in the Atmosphere , in Carbon Dioxide as Chemical Feedstock , Wiley-VCH , Weinheim , 2010 , ch. 1

2. W. B.Tolman and M.Aresta , Carbon Dioxide Reduction and Used as a Chemical Feedstock , in Activation of Small Molecules , Wiley-VCH , Weinheim , 2006 , ch. 1

3. Utilisation of CO2 as a chemical feedstock: opportunities and challenges

4. Chemical Technologies for Exploiting and Recycling Carbon Dioxide into the Value Chain

5. Recent developments in carbon dioxide utilization for the production of organic chemicals

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Pd-loaded hierarchical titanosilicalite-1 catalysts on CO2 cycloaddition with epoxides: Experimental and DFT investigations;Chemosphere;2024-03

2. Four-electron reduction of CO₂: from formaldehyde and acetal synthesis to complex transformations;Chemical Science;2024

3. Catalytic activity of silicene biflakes for CO₂ reduction: a theoretical approach;Physical Chemistry Chemical Physics;2023

4. URVA and Local Mode Analysis of an Iridium Pincer Complex Efficiently Catalyzing the Hydrogenation of Carbon Dioxide;Inorganics;2022-12-01

5. Theoretical Approaches to CO2 Transformations;Carbon Dioxide Utilization to Sustainable Energy and Fuels;2021-11-30