Solvent-shared pairs of densely charged ions induce intense but short-range supra-additive slowdown of water rotation-Reference-Cited by-同舟云学术

Solvent-shared pairs of densely charged ions induce intense but short-range supra-additive slowdown of water rotation

Published:2016 Issue:3 Volume:18 Page:1918-1930
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Vila Verde Ana¹²³⁴^ORCID,Santer Mark¹²³⁴,Lipowsky Reinhard¹²³⁴

Affiliation:

1. Max Planck Institute of Colloids and Interfaces

2. Theory and Bio-Systems Department

3. 14424 Potsdam

4. Germany

Abstract

Magnesium and sulfate ions in solvent-shared (SIP) ion pair configuration supra-additively slowdown the rotation of water molecules between them; water molecules around solvent-separated (2SIP) ion pairs show only additive slowdown.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP05726D

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5. Water Mobility: A Bridge between the Hofmeister Series of Ions and the Friction of Zwitterionic Surfaces in Aqueous Environments

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