A fluorosurfactant and photoreducible CuII-tren click catalyst: surfactant and catalytic properties at liquid/liquid interfaces

Author:

Jochyms Quentin12345,Guillot Pierre45673,Mignard Emmanuel45673,Vincent Jean-Marc123

Affiliation:

1. Univ. Bordeaux – CNRS UMR 5255

2. 33405 Talence

3. France

4. CNRS

5. LOF

6. UMR 5258

7. F33600 Pessac

Abstract

The fluorous copper(ii)-tren complex2is a powerful surfactant which strongly reduces the perfluorodecalin/water and diisopropyl ether/water interface tensions. When photoreduced by light it catalyzes the Huisgen click cycloaddition.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference38 articles.

1. Chemistry, Physical Chemistry, and Uses of Molecular Fluorocarbon−Hydrocarbon Diblocks, Triblocks, and Related Compounds—Unique “Apolar” Components for Self-Assembled Colloid and Interface Engineering

2. E. Kissa , Fluorinated Surfactants and Repellents: Second Edition, Revised and Expanded, Surfactant Science Series, Marcel Dekker, New York, 2001, vol. 97

3. Fluorocarbons and fluorinated amphiphiles in drug delivery and biomedical research

4. Handbook of fluorous chemistry, ed. J. A. Gladysz, D. P. Curran and I. T. Horváth, Wiley-VCH, Weinheim, Germany, 2004

5. I. T. Horváth (ed), Fluorous Chemistry, Top. Curr. Chem., 2012, 308, 1–411

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