Selective azide–alkyne cycloaddition reactions of azidoalkylated calixarenes-Reference-Cited by-同舟云学术

Selective azide–alkyne cycloaddition reactions of azidoalkylated calixarenes

Published:2020 Issue:17 Volume:7 Page:2432-2441
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Gorbunov Alexander¹²³⁴^ORCID,Kuznetsova Julia¹²³⁴,Deltsov Ilya¹²³⁴^ORCID,Molokanova Anastasia¹²³⁴,Cheshkov Dmitry⁵⁶⁴^ORCID,Bezzubov Stanislav⁷⁸³⁴^ORCID,Kovalev Vladimir¹²³⁴^ORCID,Vatsouro Ivan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. M. V. Lomonosov Moscow State University

3. 119991 Moscow

4. Russia

5. State Research Institute for Chemistry and Technology of Organoelement Compounds

6. 105118 Moscow

7. Kurnakov Institute of General and Inorganic Chemistry

8. Russian Academy of Sciences

Abstract

Reaction of calixarene oligo(azides) with alkynes taken in deficiency lead selectively to oligo(triazoles) under Cu(i) catalysis. Same azides react with alkynes intramolecularly under copper-free conditions forming 1,5-substituted triazole bridges.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/D0QO00650E

Reference46 articles.

1. Peptidotriazoles on Solid Phase: [1,2,3]-Triazoles by Regiospecific Copper(I)-Catalyzed 1,3-Dipolar Cycloadditions of Terminal Alkynes to Azides

2. A Stepwise Huisgen Cycloaddition Process: Copper(I)-Catalyzed Regioselective “Ligation” of Azides and Terminal Alkynes

3. 1,3-Dipolar Cycloadditions. Past and Future

4. Cu-Catalyzed Azide−Alkyne Cycloaddition

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