Molecular Pac-Man and Tacos: layered Cu(ii) cages from ligands with high binding site concentrations

Author:

McDonald Cecelia1234,Williams David W.1567,Comar Priyanka8910117,Coles Simon J.1213141516ORCID,Keene Tony D.1213141516,Pitak Mateusz B.1213141516,Brechin Euan K.8910117,Jones Leigh F.12341

Affiliation:

1. School of Chemistry

2. NUI Galway

3. Galway

4. Ireland

5. Bangor University

6. Bangor

7. UK

8. EaStCHEM School of Chemistry

9. Joseph Black Building

10. University of Edinburgh

11. Edinburgh

12. UK National Crystallographic Service

13. Chemistry

14. Faculty of Natural and Environmental Sciences

15. University of Southampton

16. England

Abstract

Sheet Metal: The deliberate in situ Schiff base condensation of two organic subunits (hydroxamic acid and phenolic aldehyde) leads to polydentate ligands capable of forming large Cu(ii) cages of nuclearities ranging from [Cu10] to [Cu30].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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