Luminescence and magnetocaloric effect of Ln4 clusters (Ln = Eu, Gd, Tb, Er) bridged by CO32− deriving from the spontaneous fixation of carbon dioxide in the atmosphere

Author:

Chen Hong-Man12345,Wang Wen-Min12345,Li Xiao-Qin678910,Chu Xiao-Ya12345,Nie Yao-Yao12345,Liu Zhen12345,Huang Shao-Xia12345,Shen Hai-Yun12345,Cui Jian-Zhong12345ORCID,Gao Hong-Ling12345

Affiliation:

1. Department of Chemistry

2. National Demonstration Center for Experimental Chemistry & Chemical Engineering Education

3. National Virtual Simulation Experimental Teaching Center for Chemistry & Chemical Engineering Education

4. Tianjin University

5. Tianjin 300072

6. Key Laboratory of Polyoxometalate Science of the Ministry of Education

7. College of Chemistry

8. Northeast Normal University

9. Changchun

10. P. R. China

Abstract

Ln4 clusters are bridged by CO32−, deriving from the spontaneous fixation of CO2. And the Gd4 complex can show MCE.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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