Analyses of sizable ZFS and magnetic tensors of high spin metallocomplexes-Reference-Cited by-同舟云学术

Analyses of sizable ZFS and magnetic tensors of high spin metallocomplexes

Published:2017 Issue:36 Volume:19 Page:24769-24791
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Yamane Takeshi¹²³⁴⁵^ORCID,Sugisaki Kenji¹²³⁴⁵^ORCID,Nakagawa Tomoki¹²³⁴⁵,Matsuoka Hideto¹²³⁴⁵,Nishio Takahisa¹²³⁴⁵,Kinjyo Shigemori¹²³⁴⁵,Mori Nobuyuki¹²³⁴⁵,Yokoyama Satoshi¹²³⁴⁵,Kawashima Chika¹²³⁴⁵,Yokokura Naoki¹²³⁴⁵,Sato Kazunobu¹²³⁴⁵,Kanzaki Yuki¹²³⁴⁵,Shiomi Daisuke¹²³⁴⁵,Toyota Kazuo¹²³⁴⁵,Dolphin David H.⁶⁷⁸⁹,Lin Wei-Ching⁶⁷⁸⁹,McDowell Charles A.⁶⁷⁸⁹,Tadokoro Makoto⁶¹⁰¹¹¹²⁵,Takui Takeji¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Molecular Materials Science

2. Graduate School of Science

3. Osaka City University

4. Osaka 558-8585

5. Japan

6. Department of Chemistry

7. The University of British Columbia

8. Vancouver

9. V6T 1Z1 Canada

10. Faculty of Science

11. Tokyo University of Science

12. Tokyo 162-0825

Abstract

The exact and genuine Zeeman perturbation based analytical expressions of the eigen-energies/-functions and the g^eff–g^true relationships for high spin metallocomplexes with sizable ZFS parameters are derived up to S = 7/2, determining the parameters for Fe^III(Cl)OEP, Co^IIOEP, and a Re^III,IV dinuclear complex.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP03850J

Reference102 articles.

1. The Porphyrins, ed. D. Dolphin, Academic Press, New York, 1978

2. Porphyrin Handbook, ed. K. M. Kadish, K. M. Smith and R. Guilard, Academic Press, 1999

3. Expanded Porphyrin with a Split Personality: A Hückel–Möbius Aromaticity Switch