Heteroleptic Ru(ii) cyclometalated complexes derived from benzimidazole-phenyl carbene ligands for dye-sensitized solar cells: an experimental and theoretical approach

Author:

Jella Tejaswi12345,Srikanth Malladi6745,Soujanya Yarasi6745,Singh Surya Prakash12345,Giribabu Lingamallu12345,Islam Ashraful891011,Han Liyuan891011,Bedja Idriss1213141516,Gupta Ravindra Kumar1213141516

Affiliation:

1. Inorganic & Physical Chemistry Division

2. CSIR-Indian Institute of Chemical Technology, and CSIR-Network Institutes for Solar Energy (CSIR-NISE)

3. Tarnaka, and CSIR-Network Institutes for Solar Energy (CSIR-NISE)

4. Hyderabad-500007

5. India

6. Molecular Modelling Group

7. CSIR-Indian Institute of Chemical Technology

8. Photovoltaic Materials Unit

9. National Institute for Materials Science

10. Tsukuba

11. Japan

12. CRC

13. Optometry Department

14. College of Applied Medical Sciences

15. King Saudi University

16. Riyadh 11433

Abstract

We have designed and synthesized heteroleptic Ru(ii) complexes based on N-heterocyclic/phenyl carbene ligand for dye-sensitized solar cells. New dyes have shown an overall conversion of efficiency of 7.63% using iodide based liquid redox electrolyte.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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