Solvent-free synthesis of a new perfluorinated MIL-53(Al) with a temperature-induced breathing effect

Author:

Morelli Venturi Diletta1ORCID,Guiotto Virginia2,D'Amato Roberto1,Calucci Lucia3ORCID,Signorile Matteo2ORCID,Taddei Marco4ORCID,Crocellà Valentina2ORCID,Costantino Ferdinando1ORCID

Affiliation:

1. Department of Chemistry, Biology and Biotechnology, Università degli Studi di Perugia, Via Elce di Sotto, 8 – 06123 Perugia, Italy

2. Department of Chemistry, NIS and INSTM Centers, Università di Torino, Via G. Quarello 15 and Via P. Giuria 7, 10125, Turin, Italy

3. ICCOM-CNR, Via G. Moruzzi 1, 56124 Pisa, Italy

4. Department of Chemistry and Industrial Chemistry, Università di Pisa, Via Giuseppe Moruzzi 13, 56124, Pisa, Italy

Abstract

A new fluorinated member of the MIL-53(Al) family, displaying a unique temperature-induced phase transition, was synthesised via a solvent-free route.

Funder

Ministero dell'Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Industrial and Manufacturing Engineering,Process Chemistry and Technology,Energy Engineering and Power Technology,Biomedical Engineering,Chemical Engineering (miscellaneous),Chemistry (miscellaneous)

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