Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption-Reference-Cited by-同舟云学术

Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption

Published:2016 Issue:17 Volume:4 Page:6259-6263
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Dey Subarna¹²³⁴,Bhunia Asamanjoy¹²³⁴,Esquivel Dolores⁵⁶⁷⁸⁹,Janiak Christoph¹²³⁴

Affiliation:

1. Institut für Anorganische Chemie und Strukturchemie

2. Heinrich-Heine-Universität Düsseldorf

3. 40204 Düsseldorf

4. Germany

5. Department of Organic Chemistry

6. Nanochemistry and Fine Chemistry Research Institute (IUIQFN)

7. Faculty of Sciences

8. University of Córdoba

9. 14071 Córdoba

Abstract

Two microporous CTFs with triptycene (TPC) and fluorene (FL) have been synthesized through a mild AlCl₃-catalyzed Friedel–Crafts reaction, with the highest surface area of up to 1668 m² g⁻¹ for non-ionothermal CTFs. CTF-TPC and CTF-FL show an excellent carbon dioxide uptake capacity of up to 4.24 mmol g⁻¹ at 273 K and 1 bar.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/TA/C6TA00638H

Reference52 articles.

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