Tuneable reduction of CO<sub>2</sub> – organocatalyzed selective formylation and methylation of amines-Reference-Cited by-同舟云学术

Tuneable reduction of CO₂ – organocatalyzed selective formylation and methylation of amines

Published:2024 Issue:1 Volume:26 Page:439-447
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Ren Changyue¹²,Terazzi Constanza¹,Werner Thomas¹³^ORCID

Affiliation:

1. Leibniz Institute for Catalysis e.V. at the University of Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany

2. College of Pharmacy, Zunyi Medical University, Zunyi 563003, China

3. Department of Chemistry, Paderborn University, Warburger Str. 100, D-33098 Paderborn, Germany

Abstract

The selective N-formylation and N-methylation of amines with carbon dioxide (CO2) catalyzed by methyltriphenylphosphonium methylcarbonate and tuned by polymethylhydrosiloxane or trimethoxysilane as reducing agents is reported.

Funder

Leibniz-Gemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D3GC03993E

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