Hypervalent-iodine-mediated oxidation followed by the acetoxylation/tosylation of α-substituted benzylamines to obtain α-acyloxy/tosyloxy ketones-Reference-Cited by-同舟云学术

Hypervalent-iodine-mediated oxidation followed by the acetoxylation/tosylation of α-substituted benzylamines to obtain α-acyloxy/tosyloxy ketones

Published:2022 Issue:35 Volume:46 Page:16832-16839
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Rupanawar Bapurao D.¹²,Mane Kishor D.¹²,Suryavanshi Gurunath¹²^ORCID

Affiliation:

1. Chemical engineering and process development division, CSIR-National Chemical Laboratory, Pune, 411 008, India

2. Academy of Scientific and Innovative Research, Ghaziabad, Uttar Pradesh, 201 002, India

Abstract

A metal-free and efficient protocol has been developed for sequential oxidation followed by acetoxylation/tosylation of α-alkylbenzylamines for the synthesis of α-acyloxy/tosyloxy ketones using hypervalent iodine(iii).

Funder

University Grants Commission

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ02271K

Reference38 articles.

1. Phenylpropanoid derivatives from Clausena harmandiana fruits

2. Metal-free one-pot α -benzoxylation of benzylic alcohols with acids or aldehydes

3. Synthesis and Biological Activities of a 3'-Azido Analogue of Doxorubicin Against Drug-Resistant Cancer Cells

4. A Novel Alkaloid Serantrypinone and the Spiro Azaphilone Daldinin D from Penicillium thymicola

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