The Pauson–Khand reaction using alkynylboronic esters: solving a long-standing regioselectivity issue-Reference-Cited by-同舟云学术

The Pauson–Khand reaction using alkynylboronic esters: solving a long-standing regioselectivity issue

Published:2016 Issue:60 Volume:52 Page:9363-9366
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

León Thierry¹²³⁴,Fernández Elena⁵⁶²³⁴

Affiliation:

1. Center for Chemical Technology of Catalonia (CTQC)

2. Marcel·lí Domingo

3. 43007 Tarragona

4. Spain

5. Departament de Química Física i Inorgànica

6. Universitat Rovira i Virgili

Abstract

The first intermolecular Pauson–Khand reaction, conducted using internal alkynylboronic esters, allows the installation of the boronic ester moiety at the β-position of the cyclopentenone with total regio- and stereoselectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC04717C

Reference32 articles.

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3. The Pauson–Khand reaction, a powerful synthetic tool for the synthesis of complex molecules

4. The Pauson–Khand Reaction: the Catalytic Age Is Here!

5. Recent Advances in the Pauson–Khand Reaction and Related [2+2+1] Cycloadditions

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