Complexation of U(vi) with benzoic acid at variable temperatures (298–353 K): thermodynamics and crystal structures of U(vi)/benzoate complexes-Reference-Cited by-同舟云学术

Complexation of U(vi) with benzoic acid at variable temperatures (298–353 K): thermodynamics and crystal structures of U(vi)/benzoate complexes

Published:2016 Issue:1 Volume:45 Page:384-391
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yang Yanqiu¹²³⁴⁵,Teat Simon J.⁶⁷⁸⁹,Zhang Zhicheng⁵⁷⁸⁹,Luo Shunzhong¹²³⁴,Rao Linfeng⁵⁷⁸⁹

Affiliation:

1. Institute of Nuclear Physics and Chemistry

2. Chinese Academy of Engineering Physics

3. Mianyang

4. China

5. Chemical Sciences Division

6. Advanced Light Source

7. Lawrence Berkeley National Laboratory

8. Berkeley

9. USA

Abstract

Thermodynamics of the U(vi) complexation with benzoic acid was studied by spectrophotometry at varied temperatures (298–353 K). A new μ₃-OH bridged U(vi)/benzoate complex crystal was synthesized, and its structure was determined by single-crystal X-ray diffractometry.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03532E

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