Understanding theZselectivity of the metal-free intermolecular aminoarylation of alkynes: a DFT study
Author:
Affiliation:
1. College of Chemistry and Molecular Engineering
2. Zhengzhou University
3. Zhengzhou
4. P. R. China
5. Institute of Chemistry, Henan Academy of Sciences
6. Zhengzhou 450002
7. P.R. China
Abstract
The unusualZselectivity of the title reaction is revealed to be determined by the inherent requirements of dynamic preference of pathways that promise theZ-geometry product, rather than the isomerization of theE-productin situ.
Funder
National Natural Science Foundation of China
China Postdoctoral Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO01093E
Reference35 articles.
1. Synthesis of Heterocycles from Alkyl 3-(Dimethylamino)propenoates and Related Enaminones
2. Aza-Knoevenagel-type condensation of secondary amides: direct access to N-monosubstituted β,β-difunctionalized enamines
3. A Practical Synthesis of Indoles via a Pd-Catalyzed C–N Ring Formation
4. Direct C-Arylation of β-Enamino Esters and Ketones with Arynes
5. Metal-Free Intermolecular Aminoarylation of Alkynes
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