The path towards type V deep eutectic solvents: inductive effects and steric hindrance in the system <i>tert</i>-butanol + perfluoro <i>tert</i>-butanol-Reference-Cited by-同舟云学术

The path towards type V deep eutectic solvents: inductive effects and steric hindrance in the system tert-butanol + perfluoro tert-butanol

Published:2023 Issue:16 Volume:25 Page:11227-11236
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Vaz Inês C. M.¹²^ORCID,Lobo Ferreira Ana I. M. C.¹^ORCID,Silva Gonçalo M. C.³⁴^ORCID,Morgado Pedro³^ORCID,Abranches Dinis O.⁴^ORCID,Bastos Margarida¹^ORCID,Santos Luís M. N. B. F.¹^ORCID,Filipe Eduardo J. M.³^ORCID,Coutinho João A. P.⁴^ORCID

Affiliation:

1. CIQUP, Institute of Molecular Sciences (IMS) – Departamento de Química e Bioquímica, Faculdade de Ciências da Universidade do Porto, Rua do Campo Alegre, P-4169-007 Porto, Portugal

2. Laboratoire de Chimie de l’ENS Lyon, CNRS and Université de Lyon, 46 allée d’Italie, 69364 Lyon, France

3. CQE, Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Lisboa, Portugal

4. CICECO – Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Aveiro, Portugal

Abstract

The electron withdrawal effect of the fluorine atoms in perfluoro-tert-butanol leads to a large polarity asymmetry. This results in strong hydrogen bonding when mixed with a regular alcohol and is explored to prepare a type V deep eutectic solvent.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00701D

Reference66 articles.

1. Everything You Wanted to Know about Deep Eutectic Solvents but Were Afraid to Be Told

2. Insights into the Nature of Eutectic and Deep Eutectic Mixtures

3. Deep Eutectic Solvents (DESs) and Their Applications

4. Deep eutectic solvents and their applications as green solvents

5. Phenolic hydrogen bond donors in the formation of non-ionic deep eutectic solvents: the quest for type V DES

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